Organic · Pericyclic Reactions

Pericyclic Reactions

CSIR-NET Chemical Sciences revision note · 6 sections · about 466 words

Exam-focused revision notes on Pericyclic Reactions for CSIR-NET Chemical Sciences, GATE Chemistry and IIT-JAM — the core concepts, the formulas worth memorising, the traps that cost marks, and a quick-recall table.

The core idea

Reactions that go through a cyclic transition state with no intermediates — concerted, single-step and stereospecific. Their outcome is fixed by orbital symmetry, and it flips between thermal and photochemical conditions.

What this note covers

  • 1The core idea
  • 2Electrocyclic reactions
  • 3Cycloaddition reactions
  • 4Sigmatropic rearrangements
  • 5Common traps students miss
  • 6Woodward–Hoffmann selection rules (recall table)

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The remaining 5 sections — including the worked examples, the common-traps list and the quick-recall table — are part of ChemVidya Full Access, along with 6,000+ practice questions.

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