Inorganic · Electronic Spectra

Electronic Spectra of Complexes

CSIR-NET Chemical Sciences revision note · 11 sections · about 588 words

Exam-focused revision notes on Electronic Spectra of Complexes for CSIR-NET Chemical Sciences, GATE Chemistry and IIT-JAM — the core concepts, the formulas worth memorising, the traps that cost marks, and a quick-recall table.

The core idea

The colour of transition-metal complexes comes from electronic transitions. Two families matter: d–d transitions (weak, give pale colours) and charge-transfer bands (intense, give deep colours).

What this note covers

  • 1The core idea
  • 2d–d transitions
  • 3Selection rules
  • 4Free-ion terms & ground term
  • 5Orgel diagrams
  • 6Tanabe–Sugano diagrams
  • 7Charge-transfer (CT) bands
  • 8Nephelauxetic effect
  • 9Jahn–Teller distortion (brief)
  • 10Common traps students miss
  • 1130-second recall table

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